Formation and surface reactions of oxide supported rhodium carbonyl complexes
โ Scribed by Michael S. Scurrell
- Publisher
- Elsevier Science
- Year
- 1980
- Weight
- 693 KB
- Volume
- 10
- Category
- Article
- ISSN
- 0304-5102
No coin nor oath required. For personal study only.
๐ SIMILAR VOLUMES
The main purpose of the development of an Rh(I) Carbonyl Phosphine force field was to predict the molecular structure of Rh(I) complexes as well as to compute possible intermediates or transition states during the oxidative addition of CH 3 I to these complexes.
Alumina-supported manganese oxide catalysts as well as the parent formates were characterized my means of FTIR spectroscopy and nitrogen physisorption. Two different manganese formate solutions are used for the impregnation of alumina (4.8 and 8.0 mass%). The infrared bands in the high frequency reg
Genesis of silica-supported [FesRhC(CO)t~]-and [Fe4RhC(CO)~4]-clusters with interstitial carbon atoms have been investigated in CO, syn-gas and Ar media. Complete conversion of the former cluster to the latter was obtained at 50ยฐC in any medium, with [Fe4RhC(CO)I4] cluster yielding Fe4Rh2C(CO)I 6 an