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Formation and Structure of a Platinum(II) Complex Containing Two trans Nonstabilized Phosphorus Ylide Ligands: Evidence for Reversible Ylide Dissociation

✍ Scribed by Dub, Pavel A.; Béthegnies, Aurélien; Daran, Jean-Claude; Poli, Rinaldo

Book ID
120394008
Publisher
American Chemical Society
Year
2012
Tongue
English
Weight
313 KB
Volume
31
Category
Article
ISSN
0276-7333

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Platinum-Assisted Addition of Carbonyl-S
Platinum-Assisted Addition of Carbonyl-Stabilized Phosphorus Ylides to Pentafluorobenzonitrile and Acetonitrile To Give Platinum(II) Complexes Containing Iminophosphorane and/or N-Bonded β-Imino Phosphorus Ylide Ligands. Crystal and Molecular Structures of trans- [PtCl 2 { E- NHC(C 6 F 5 )C(PPh 3 )C(O)Me} 2 ] and trans- [PtCl 2 { E -N(PPh 3 )C(C 6 F 5 )CHCO 2 Et}{ E- NHC(C 6 F 5 )C(PPh 3 )CO 2 Et}] †
✍ Vicente, José; Chicote, María Teresa; Beswick, Michael A.; Ramirez de Arellano, 📂 Article 📅 1996 🏛 American Chemical Society 🌐 English ⚖ 289 KB