There is an upsurge of interest in contemporary theoretical and experimental research to unravel the structural details of water clusters. [1Β±8] The clusters are believed to be the perfect means for characterizing the structural changes and bonding mechanisms in passing from isolated molecules to a
Formation and Structural Characterisation of an Unusual Cyclic HexamericOxotitanium Complex
β Scribed by Tim Kemmitt; Najeh I. Al-Salim; Graeme J. Gainsford
- Publisher
- John Wiley and Sons
- Year
- 1999
- Tongue
- English
- Weight
- 265 KB
- Volume
- 1999
- Category
- Article
- ISSN
- 1434-1948
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β¦ Synopsis
consists of a ring of six [TiO 5 N] octahedra, edge bridged by Β΅ 2 -oxide and a Β΅ 2 -alkoxide arm of the aminoalkoxide ligand. was obtained by the controlled hydrolysis of the Ti(MDEA) 2 complex and analysed by X-ray diffraction. The compound [a] Industrial Research Ltd, H(25A)β’β’β’O(14), Hβ’β’β’O Ο 233 pm}. Two molecules of di-P.O. Box 31Οͺ310,
π SIMILAR VOLUMES
The compounds [Cu II 2 Co III 2 (H 2 dea) 2 (dea) 4 ]X 2 (Solv) n [X = Cl (1), Br (2), SCN (3), O 2 CMe (4), I ( 5); Solv = H 2 O or/and CH 3 OH, DMF, n = 1-4] were synthesised by the reaction of zero-valent copper with cobalt(II) salts in non-aqueous (CH 3 OH, DMF, DMSO) solutions of diethanolamine