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Formation and rearrangement of ipso intermediates in aromatic free-radical chlorination reactions

โœ Scribed by Everly, Charles R.; Traynham, James G.

Book ID
125500619
Publisher
American Chemical Society
Year
1978
Tongue
English
Weight
264 KB
Volume
100
Category
Article
ISSN
0002-7863

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โœ Jordan M. Cummins; Ulf-H. Dolling; Alan W. Douglas; Sandor Karady; William R. Le ๐Ÿ“‚ Article ๐Ÿ“… 1999 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 224 KB

Products derived from the homolysis of the aromatic C-I bond of ortho-iodobenzophenones by photolysis or tributyltin radicals indicate 1,5-hydrogen migration. The reactions include iodine migration, hydrogen abstraction and arylation.