Tokyo, Hongo, Bunkyo-ku, (3-Nitrostyrenes are diprotonated on the nitro group to yield N,N-dihydroxyiminium-benzyl dications in trifluoromethanesulfonic acid. These dications comprise a new class of reagents that can react with benzene. The reaction is dependent on the substituent (H or alkyl group)
Formation and reaction of N-substituted peroxycarboximidic acids from α-azobenzyl hydroperoxides by pyridine-catalyzed reaction
✍ Scribed by Takahiro Tezuka; Takashi Otsuka; Pi-Chao Wang; Mie Murata
- Publisher
- Elsevier Science
- Year
- 1986
- Tongue
- French
- Weight
- 259 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0040-4039
No coin nor oath required. For personal study only.
✦ Synopsis
a-Azobenzyl hydroperoxides (4) isomerize to N-(4-bromoanilino)peroxycarboximidic acids (21, which are transformed into benzoic acids (a), by the pyridine-catalyzed reaction.
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