Formation and properties of the trivalent nickel-ethylene diamine tetra-acetic acid (EDTA) complex in aqueous solutions: A pulse-radiolytic study

The Redox Chemistry of (N1-[3-(2-aminoet

The Redox Chemistry of (N1-[3-(2-aminoethylimino)-1,1-dimethylbutyl]ethane-1,2-diamine)nickel(II) Perchlorate, NiIIL1(ClO4)2, in Aqueous Solutions –A Pulse Radiolytic and an Electrochemical Study

✍ Yael Albo; Eric Maimon; Israel Zilbermann; Magal Saphier; Haim Cohen; Dan Meyers 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 172 KB

## Abstract The ligand (N^1^‐[3‐(2‐aminoethylimino)‐1,1‐dimethylbutyl]ethane‐1,2‐diamine), L^1^, induces a high ligand field on the central Ni^II^ ion. Thus it is relatively easy to oxidize(Ni^II^L^1^)^2+^. However, the kinetic stability of the Ni^III^L^1^ complexes is considerably lower than that