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Formation and oxidation of 1:1 adducts of tetrahalo-1,2-benzoquinones and 1,3-diene

✍ Scribed by Sung Sik Kim; Young Hyun Yu; Sang Chul Shim; In Ho Cho

Book ID
103399974
Publisher
Elsevier Science
Year
1994
Tongue
French
Weight
247 KB
Volume
35
Category
Article
ISSN
0040-4039

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Oxidation of the title compounds, in contrast to that of ''normal'' (Z,Z)-buta-1,3-diene-1,4-dithiolates, does not lead to the formation of 1,2-dithiins. Thus, the aliphatic diaminodithiolates 7 and 8 were converted into the (E)-2-butenedithioamides 12 and 15 as a result of resonance stabilization o