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Formation and Isolation of a Covalent Intermediate during the Glutaminase Reaction of a Class II Amidotransferase †

✍ Scribed by Schnizer, Holly G.; Boehlein, Susan K.; Stewart, Jon D.; Richards, Nigel G. J.; Schuster, Sheldon M.

Book ID
126809250
Publisher
American Chemical Society
Year
1999
Tongue
English
Weight
82 KB
Volume
38
Category
Article
ISSN
0006-2960

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## Abstract Reaction of the diphosphanylamine 2,6‐{(Ph~2~P)~2~N}~2~C~5~H~3~N with four equivalents of Au(tht)Cl (tht = tetrahydrothiophene) affords the tetragold complex 2,6‐{(ClAuPh~2~P)~2~N}~2~C~5~H~3~N in high yield. Decomposition of the tetragold compound results in the formation of the digold