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Formation and distribution of 2,4-dihydroxy-2,5-dimethyl-3(2H)-thiophenone, a pigment, an aroma and a biologically active compound formed by the Maillard reaction, in foods and beverages

✍ Scribed by Furusawa, Rina; Goto, Chiaki; Satoh, Miki; Nomi, Yuri; Murata, Masatsune

Book ID: 120846749
Publisher: The Royal Society of Chemistry
Year: 2013
Tongue: English
Weight: 602 KB
Volume: 4
Category: Article
ISSN: 2042-6496
DOI: 10.1039/C3FO30367E

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Formation of .eta.1-iminoacyl compounds

Formation of .eta.1-iminoacyl compounds by insertion of isonitriles into pentamethylcyclopentadienyl-tetramethylfulvene compounds of titanium and zirconium. Intramolecular C-H activation of a pentamethylcyclopentadienyl group to give a tridentate ligand with two bridged cyclopentadienyl rings and a titanium-vinyl bond in the bridge. Molecular structure of [cyclic][.eta.5:.eta.1:.eta.5-C5Me4CH2C(NHXyl):CN(Xyl)CH2C5Me4]TiCl and [cyclic]Cp*[.eta.5:.eta.1-C5Me4CH2C(:NXyl)C(:NXyl)]ZrCl (Xyl=2,6-Me2C6H3)

✍ Fandos, Rosa.; Meetsma, Auke.; Teuben, Jan H. 📂 Article 📅 1991 🏛 American Chemical Society 🌐 English ⚖ 916 KB