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Formation and analysis of a polyimide layer in composite membranes

✍ Scribed by G. A. Polotskaya; V. P. Sklizkova; N. D. Kozhurnikova; G. K. Elyashevich; V. V. Kudryavtsev


Publisher
John Wiley and Sons
Year
2000
Tongue
English
Weight
220 KB
Volume
75
Category
Article
ISSN
0021-8995

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✦ Synopsis


Composite membranes containing a thin-film layer of aromatic polyimides (PI) ensure an advantageous combination of selectivity and permeability in gas separation. A series of rigid-chain PI with different chemical structures were studied as a thin active layer. Composite membranes were prepared by coating a solution of poly-(amic acid) (PAA) and an imidization catalyst on a poly(phenylene oxide) (PPO) support with pores filled by decane. The subsequent stage of solid-state catalytic transformation of the PAA/PPO membrane into the PI/PPO membrane determines the specific structure of the PI layer and the transport properties of the PI/PPO composite membranes. The structure of composite membranes was determined by scanning electron microscopy and analyzed in the terms of the resistance model of gas transport in composite membranes.


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