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Formate-reducedE. coliformate dehydrogenase H: the reinterpretation of the crystal structure suggests a new reaction mechanism

✍ Scribed by Hans C. A. Raaijmakers; Maria João Romão

Book ID
106231981
Publisher
John Wiley and Sons
Year
2006
Tongue
English
Weight
355 KB
Volume
11
Category
Article
ISSN
1432-1327

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The mechanisms of the reactions of diborane with ammonia have been investigated by ab initio molecular orbital methods. The activation barrier of the formation of aminoborane, H,&NHr, from the adduct, H,B : NHs, of borane and ammonia is high (over 40 kcal/mol), because it is a reaction essentially