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Formate as a Surface Probe for Ruthenium Nanoparticles in Solution 13C NMR Spectroscopy

✍ Scribed by Karaked Tedsree; Adam T. S. Kong; Shik Chi Tsang

Publisher
John Wiley and Sons
Year
2009
Tongue
English
Weight
355 KB
Volume
121
Category
Article
ISSN
0044-8249

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✦ Synopsis

Abstract

Die Adsorption von Ameisensäure auf unterschiedlich großen Ru‐Nanopartikeln ermöglicht die Differenzierung verschieden gebundener Formiatspezies durch ^13^C‐NMR‐Spektroskopie in Lösung (siehe Bild). Die chemischen Verschiebungen sind ähnlich zu denen von metallorganischen Analoga; dies lässt den Schluss zu, dass Formiat als Sonde zur Unterscheidung von Oberflächenmerkmalen gelöster Metallnanopartikel mit guter Quantifizierung und Auflösung dienen kann.magnified image

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