In the preceding paper. the syntheses of the optically active two segments (+)-2 and (-)-2 having most of chiral centers involved in erythronolide A were reported. In this report, coupling reaction of these two segments and the subsequent elaboration leading to carbamate 1. a key intermediate in W
Formal total synthesis of erythromycin A. Part III. Synthesis of Woodward's carbamate key intermediate from a 1,7-dioxaspiro[5.5]undecane derivative of erythronolide A
✍ Scribed by Bernet, Bruno; Bishop, Paul M.; Caron, Maurice; Kawamata, Takeshi; Roy, Bernard L.; Ruest, Luc; Sauvé, Gilles; Soucy, Pierre; Deslongchamps, Pierre
- Book ID
- 126765579
- Publisher
- NRC Research Press
- Year
- 1985
- Tongue
- French
- Weight
- 167 KB
- Volume
- 63
- Category
- Article
- ISSN
- 0008-4042
- DOI
- 10.1139/v85-470
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