Carbohydrate based formal synthesis of s
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Mukund K Gurjar; Dandepally Srinivasa Reddy
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Article
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2002
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Elsevier Science
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French
⚖ 172 KB
A synthesis of stemoamide has been achieved from D-glucose. The stereocontrolled allylation under Barbier reaction conditions led to the installation of the 2-pyrrolidinone ring at C-3 followed by a ring-closing metathesis approach to construct the azepine ring system.