Formal Synthesis of (-)-Clavepictine A and (+)-Clavepictine B from a Sulfinimine (N-Sulfinylimine)-Derived Chiral Building Block
β Scribed by A. Davis, Franklin; Xu, He
- Book ID
- 118270700
- Publisher
- Japan Institute of Heterocyclic Chemistry
- Year
- 2012
- Tongue
- English
- Weight
- 787 KB
- Volume
- 84
- Category
- Article
- ISSN
- 0385-5414
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π SIMILAR VOLUMES
## Abstract For Abstract see ChemInform Abstract in Full Text.
TheN-Benzylirninederivedfrom2,3-di-O-benzyl-D-glyceraidehyde reactswithDanishefsky's diene to afford the correspondinghetero Diels-Alder adductwith a high diaatereoaelectivity. This compoundcanbe.transformed to enantiomerically pure(2R)40xopipecolicacid 01997 EIsevierScienceLtd. The piperidine ring
Asymmetric Hetero Diels-Alder Reaction of N-Benzylimines Derived from ( R)-Glyceraldehyde: A New Approach to Homochiral Piperidine Building Blocks and Its Application to the Synthesis of (2R)-4-Oxopipecolic Acid. -The D-glyceraldehyde derived N-benzyl imine (I) undergoes a highly diastereoselective