✦ LIBER ✦

Formal Synthesis of (-)-Apicularen A.

✍ Scribed by Benjamin R. Graetz; Scott D. Rychnovsky

Publisher: John Wiley and Sons
Year: 2004
Weight: 61 KB
Volume: 35
Category: Article
ISSN: 0931-7597
DOI: 10.1002/chin.200401197

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✦ Synopsis

Abstract

For Abstract see ChemInform Abstract in Full Text.

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## Abstract Reactions between amide anions and propanal derivatives containing benzolactone components at their 3‐positions produced hemiaminals, which were dehydrated via the corresponding acetates to provide the apicularen A analogues **21**, **29**, **34**, **38**, and **41**. Of these, **21** a