The normal coordinate and force field analysis we have previously undertaken for the in-plane motions of tellurophene and selenophene is completed in this paper with the calculation of the A2 and B2 (A") modes due to the out-of-plane bendings in these molecules. Force and interaction constants and t
Force field calculation of the in-plane fundamental motions of tellurophene and selenophene
โ Scribed by Aldo Santucci; Giulio Paliani; Rosario Sergio Cataliotti
- Book ID
- 103905732
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 516 KB
- Volume
- 41
- Category
- Article
- ISSN
- 1386-1425
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โฆ Synopsis
A valence force field has been derived for the 8A1 and 7B, in-plane vibrations of selenophene and tellurophene. The force constants' refinement has been derived from experimental frequencies previously obtained for selenophene and tellurophene. Numerical values of the force constants show that there is a noticeable variation in the ring-aromaticitv of these congeners, going from thiophene to tellurophene, as previously established by diffeyent techniques.
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