Forbidden transitions (δM = 2) induced by an axial crystal field in electron paramagnetic resonance of 3d5 ions in II–VI compounds

✍ Scribed by B. Clerjaud; C. Marti; A. Billmann

• Publisher: John Wiley and Sons
• Year: 1971
• Tongue: English
• Weight: 314 KB
• Volume: 44
• Category: Article
• ISSN: 0370-1972
• DOI: 10.1002/pssb.2220440228

✦ Synopsis

Abstract

For certain angles between the magnetic field and the c‐axis of the crystal, “forbidden” magnetic dipolar transitions Δ__M__ = 2, Δ__m__ = C, ± 1 (M and m electronic and nuclear azimuthal quantum numbers) can be induced by an axial crystal field in electron paramagnetic resonance. These transitions are observed in ZnS/Mn^2+^, ZnO/Fe^3+^, and ZnO/Mn^2+^ single crystals and compared with theoretical and experimental results.