Forbidden electronic transitions of P2 in solid neon

✍ Scribed by L.A. Heimbrook; M. Rasanen; V.E. Bondybey

• Publisher: Elsevier Science
• Year: 1985
• Tongue: English
• Weight: 483 KB
• Volume: 120
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(85)87048-2

✦ Synopsis

Se\Weral [orbidden eleclronic lransilions or P2 in solid neon are examined. All of the six observed electronics~nt~ of Pz are found IO be remarkably unshifted and unperturbed by lhe matrix. While some absorplions cxhibil sharp zero-phonon lines, olhers are characterized by broad, intense phonon sidebands. This is shown LO be a consequence of the orbitally forbidden nalurc of the corresponding nansilions.