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Folding and unfolding of a trirhodium chain about an isocyanide ligand. Structure of [Rh3{.mu.-(Ph2PCH2)2PPh}2(n-C4H9NC)5CO]3+ as a solid and in solution

✍ Scribed by Balch, Alan L.; Fossett, L. Alan.; Olmstead, Marilyn M.

Book ID: 126070458
Publisher: American Chemical Society
Year: 1987
Tongue: English
Weight: 441 KB
Volume: 6
Category: Article
ISSN: 0276-7333
DOI: 10.1021/om00151a042

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📜 SIMILAR VOLUMES

Preparation and structure of [Rh3(.mu.-[

Preparation and structure of [Rh3(.mu.-[Ph2PCH2)2PPh]2(.mu.-CO)(CO)(.mu.-X)X][BPh4] (X = chlorine, bromine, or iodine), a ligand-poor set of trirhodium clusters

✍ Balch, Alan L.; Fossett, L. Alan.; Guimerans, Rosalvina R.; Olmstead, Marilyn M. 📂 Article 📅 1985 🏛 American Chemical Society 🌐 English ⚖ 964 KB

Fluxional molecular A-frames containing

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Additions and Corrections - Synthesis of

Additions and Corrections - Synthesis of triangular mixed-metal clusters by the addition of copper electrophiles to an electron-rich rhodium-rhodium bond. X-ray crystal structures of [Rh2(.eta.-C5H5)2(.mu.-CO)(.mu.-Ph2PCH2PPh2)(.mu.-CuI)] and [Rh2(.eta.-C5H5)2(.mu.-CO)(.mu.-Ph2PCH2PPh2)(.mu.-AgO2CCF3)] [Erratum to document cited in CA107(23):217829Q]

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Reaction of the technetium(I)carbonyl co

Reaction of the technetium(I)carbonyl complexes [Tc(PMe2Ph)3(CO)2Cl] and [Tc(PPh3)2(CO)3Cl] toward pseudo-allyl ligands such as triazenido, formamidinato, and acetamidinato. Crystal structures of [Tc(PMe2Ph)2(CO)2(p-CH3C6H4N:N:NC6H4CH3-p)] and [Tc(PMe2Ph)2(CO)2(C6H5N:C(CH3):NC6H5)]

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✍ Nucciarone, Donato.; Taylor, Nicholas J.; Carty, Arthur J. 📂 Article 📅 1986 🏛 American Chemical Society 🌐 English ⚖ 427 KB

The addition of small molecules to (.eta

The addition of small molecules to (.eta.-C5H5)2Rh2(CO)(CF3C2CF3). 3. The formation of a bridging acrylamide ligand on a dirhodium center by the cycloaddition of nitrenes, carbon monoxide, and an alkyne. X-ray crystal structure of (.eta.-C5H5)2Rh2[.mu.-.eta.3C(CF3)C(CF3)C(O)N(Ph)]

✍ Dickson, Ron S.; Nesbit, Rhonda J.; Pateras, Helen.; Baimbridge, Wayne.; Patrick 📂 Article 📅 1985 🏛 American Chemical Society 🌐 English ⚖ 967 KB