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Folded and extended structures of homooligopeptides from .alpha.,.alpha.-dialkylated glycines. A conformational energy computation and x-ray diffraction study

โœ Scribed by Benedetti, Ettore; Toniolo, Claudio; Hardy, Paul; Barone, Vincenzo; Bavoso, Alfonso; Di Blasio, Benedetto; Grimaldi, Patrizio; Lelj, Franceso; Pavone, Vincenzo


Book ID
125942760
Publisher
American Chemical Society
Year
1984
Tongue
English
Weight
815 KB
Volume
106
Category
Article
ISSN
0002-7863

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Conformational energy computations on a derivative and a homo-dipeptide of C"\*"-diethylglycine were performed. In both cases the Nand C-terminal groups are blocked as acetamido and methylamido moieties, respectively. It was found that the C"3"-diethylglycine residues are conformationally restricted