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Fluxionality and Phosphane Arm-off Reactions of Octahedral Ruthenium(II) Complexes with the Tripodal Polyphosphane MeC(CH2PPh2)3

✍ Scribed by Claudia Landgrafe; William S. Sheldrick; Marc Südfeld


Publisher
John Wiley and Sons
Year
1998
Tongue
English
Weight
718 KB
Volume
1998
Category
Article
ISSN
1434-1948

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Various β-, γ-, and δ-alkynols have been reacted with the cedented seven-membered oxacarbene ring. The rheniumassisted δ-alkynol to 2-oxacyloheptylidene rearrangement 16e Ϫ fragment [(triphos)Re(CO) 2 ] + generated in situ by H 2 elimination from [(triphos)Re(CO) 2 (η 2 -H 2 )]BF 4 [triphos = procee