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Fluxional rhenium(I) tricarbonyl halide complexes of substituted pyrazolylpyridine ligands. Nuclear magnetic resonance studies of 1,4 metallotropic shifts

✍ Scribed by M. Angeles; M. Garcia; Andrew Gelling; Darren R. Noble; Keith G. Orrell; Anthony G. Osborne; Vladimir Šik


Book ID
103653897
Publisher
Elsevier Science
Year
1996
Tongue
English
Weight
524 KB
Volume
15
Category
Article
ISSN
0277-5387

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A series of rhenium(I) tricarbonyl halide complexes of pyridyl 28Ϫ33 kJ mol Ϫ1 . In the pyridyl dicarboxamide and -dithioamide metal chelate complexes metallotropic shifts occur mono-and di-carboxamides and -thioamides has been studied by dynamic NMR techniques. Oxygen coordination between the three