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Fluorotetraphenylbismuth: A New Reagent for Efficient Regioselective α-Phenylation of Carbonyl Compounds

✍ Scribed by Ooi, Takashi; Goto, Ryoji; Maruoka, Keiji


Book ID
120528160
Publisher
American Chemical Society
Year
2003
Tongue
English
Weight
58 KB
Volume
125
Category
Article
ISSN
0002-7863

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## Chlorotrimethylsilane Nitryl chloride Density functional theory a b s t r a c t A mixture of chloro/bromotrimethylsilane and nitrate salt is found to be an effective reagent system for the a-chlorination/bromination of carbonyl compounds. The reaction occurs under mild conditions yielding the pr