(Fluoroorgano)fluoroboranes and -borates. Part 9. Highly Efficient Cross-Coupling Reactions with the Perfluoroorganotrifluoroborate Salts K [RFBF3] (RF=C6F5, CF2=CF).

Highly efficient cross-coupling reaction

Highly efficient cross-coupling reactions with the perfluoroorganotrifluoroborate salts K [RFBF3] (RF=C6F5, CF2CF)

✍ H.-J. Frohn; N.Yu. Adonin; V.V. Bardin; V.F. Starichenko 📂 Article 📅 2002 🏛 Elsevier Science 🌐 French ⚖ 120 KB

Potassium pentafluorophenyl-and trifluorovinyltrifluoroborates, both containing electron-poor organo groups, reacted with iodobenzene and p-substituted iodobenzenes in the presence of palladium compounds and stoichiometric amounts of silveroxide to the fluorinated cross-coupling products in very goo