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Fluoroalkyl- and 3-(Fluoroalkoxy)propylpolysiloxanes

✍ Scribed by STEWARD, OMAR W.; PIERCE, OGDEN R.

Book ID
127122886
Publisher
American Chemical Society
Year
1961
Tongue
English
Weight
587 KB
Volume
26
Category
Article
ISSN
0022-3263

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✍ Francisco Palacios; Concepción Alonso; Marta Rodríguez; Eduardo Martínez de Mari 📂 Article 📅 2005 🏛 John Wiley and Sons 🌐 English ⚖ 161 KB 👁 1 views

## Abstract A method for the preparation of 3‐(fluoroalkyl)‐substituted 2‐azabutadienes **5** by aza‐Wittig reaction of __N__‐vinylic 3‐(fluoroalkyl)phosphazenes **4** and aldehydes is reported. Thermal 6π‐electrocyclization of these azadienes gives 3‐(fluoroalkyl)‐substituted isoquinolines **6**.