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Fluorine Segregation Controls the Solid-State Organization and Electronic Properties of Ni and Au Dithiolene Complexes: Stabilization of a Conducting Single-Component Gold Dithiolene Complex

✍ Scribed by O.J. Dautel; M. Fourmigué; E. Canadell; P. Auban-Senzier


Publisher
John Wiley and Sons
Year
2002
Tongue
English
Weight
213 KB
Volume
12
Category
Article
ISSN
1616-301X

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✦ Synopsis


Results and Discussion

Oxidation of 2 with tetrafluorotetracyano-quinodimethane (TCNQF 4 ) in CH 3 CN afforded the one-electron oxidation product (Scheme 1), i.e., the neutral complex, [Ni(F 2 pdt) 2 ] 0 (3) ±