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Fluorination and fluorodemercuration of aromatic compounds with acetyl hypofluorite

✍ Scribed by Visser, Gerard W. M.; Bakker, Cees N. M.; Van Halteren, Bert W.; Herscheid, Jacobus D. M.; Brinkman, Gerard A.; Hoekstra, Arend


Book ID
126493657
Publisher
American Chemical Society
Year
1986
Tongue
English
Weight
574 KB
Volume
51
Category
Article
ISSN
0022-3263

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Reaction of acetyl hypofluorite with pyr
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The regiospecific syn-addition of acetyl hypofluorite to glycals derived from pentopyranoses led to mixtures of stereoisomers. Stereospecific reactions occurred with furanoid glycals, the direction of addition being governed by the nature of the substituent at C-3. Whereas a benzyloxy group caused a