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Fluorinated ketene dithioacetals. 2. Synthesis of 2-hydroperfluoro acid derivatives from perfluoroketene dithioacetals

โœ Scribed by Muzard, Murielle; Portella, Charles


Book ID
121325523
Publisher
American Chemical Society
Year
1993
Tongue
English
Weight
389 KB
Volume
58
Category
Article
ISSN
0022-3263

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Fluorinated ketene dithioacetals. Part 7
โœ J.-P Bouillon; Yu.G Shermolovich; C Portella ๐Ÿ“‚ Article ๐Ÿ“… 2001 ๐Ÿ› Elsevier Science ๐ŸŒ French โš– 76 KB

Esters of b-bromo or b-chloro perfluorodithiocrotonic acid were prepared from corresponding ketenedithioacetal with anhydrous magnesium halides. These new polyfluorinated dithiocarboxylates are good dienophiles reacting selectively via the C S bond.