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Fluorinated Chiral Secondary Amines as Catalysts for Epoxidation of Olefins with Oxone.

โœ Scribed by Chun-Yu Ho; Ying-Chun Chen; Man-Kin Wong; Dan Yang


Publisher
John Wiley and Sons
Year
2005
Weight
40 KB
Volume
36
Category
Article
ISSN
0931-7597

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โœ Loubna Gharnati; Olaf Walter; Ulrich Arnold; Manfred Dรถring ๐Ÿ“‚ Article ๐Ÿ“… 2011 ๐Ÿ› John Wiley and Sons ๐ŸŒ English โš– 434 KB

## Abstract Several pentaโ€ and hexaalkylated guanidiniumโ€based ionic liquids (GILs) were tested as solvents for the epoxidation of cyclooctene using the Venturello catalyst, [(C~8~H~17~)~3~N(CH~3~)]~3~[PO~4~{WO(O~2~)~2~}~4~], and hydrogen peroxide as the oxidant. Epoxide yields were obtained in a b