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Fluorimetric Flow-Through Sensing of Quinine and Quinidine

✍ Scribed by Ortega-Algar, Silvia ;Ramos-Martos, Natividad ;Molina-D�az, Antonio

Book ID
106196413
Publisher
Springer-Verlag
Year
2004
Weight
88 KB
Volume
147
Category
Article
ISSN
0344-838X

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Organocatalytic asymmetric synthesis of
Organocatalytic asymmetric synthesis of quinine and quinidine
✍ Shaheen M. Sarkar; Yuko Taira; Ayako Nakano; Keisuske Takahashi; Jun Ishihara; S 📂 Article 📅 2011 🏛 Elsevier Science 🌐 French ⚖ 513 KB

Quinine and quinidine were synthesized by a highly enantio-and stereoselective approach starting from a proline-catalyzed asymmetric cycloaldolization of benzyl bis(2-formylethyl)carbamate which gave a 70:30 mixture of (3R,4R)-N-Cbz-3-hydroxymethyl-4-hydroxypiperidine (96% ee) and its 4S-epimer (92%