Kinetics and mechanism of oxidation of L-serine by manganese(III) ions have been studied in aqueous sulfuric acid medium at Manganese(III) sulfate was prepared by an 323 K. electrolytic oxidation of manganous sulfate in aqueous sulfuric acid. The dependencies of the reaction rate are: an unusual one
Fluoride assisted stabilization of vanadium(III) and manganese(III) in aqueous medium and efficacy of new fluorochromate(VI) oxidants
✍ Scribed by Mihir K. Chaudhuri; Pradip C. Paul; Pendyala Srinivas
- Publisher
- Elsevier Science
- Year
- 1991
- Tongue
- English
- Weight
- 53 KB
- Volume
- 54
- Category
- Article
- ISSN
- 0022-1139
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The kinetics of oxidation of c~,/?-unsaturated alcohols (UA's), such as prop-2-ene-l-ol, but-2-ene-l-ol and 3phenyl-prop-2-ene-l-ol, by manganese(III) acetate in aqueous H2SO 4 at constant ionic strength and different acidities has been studied. The reaction was found to proceed through an outer sph
## Abstract Kinetic studies on the oxidation of 2‐mercaptosuccinic acid by dinuclear [Mn~2~^III/IV^(μ‐O)~2~(cyclam)~2~](ClO~4~)~3~] (1) (abbreviated as Mn^III^–Mn^IV^) (cyclam = 1,4,8,11‐tetraaza‐cyclotetradecane) have been carried out in aqueous medium in the pH range of 4.0–6.0, in the presence o