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Fluoride as leaving group in SRN1 reactions of a tetrasubstituted-1,4-benzoquinone

✍ Scribed by Michel P. Crozet; Luc Giraud; Jean-François Sabuco; Patrice Vanelle


Publisher
Elsevier Science
Year
1992
Tongue
French
Weight
132 KB
Volume
33
Category
Article
ISSN
0040-4039

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✦ Synopsis


2-Fluoromerhyl-35,6-trimethyl-1,4-benzoquinone was synthesized and its reactivity in SRNl reactions compared to the reacriviry of the chloro derivative previously described. This srudy reports the first examples of the displacement offluoride in SRNI reactions involving a substitutron at an Sp3 carbon atom.


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