✦ LIBER ✦

Fluorescent states of exciplex and charge-transfer complexes: experimental evidence for an identical fluorescent state

✍ Scribed by M. Itoh; T. Mimura

Publisher: Elsevier Science
Year: 1974
Tongue: English
Weight: 410 KB
Volume: 24
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(74)80178-8

No coin nor oath required. For personal study only.

✦ Synopsis

The ercipIex (above = 170°K) and the charge-transfer (CT) complex (below = 130°K) fluorescences were observed in a nonpolar solution of 9,l O-dicyanoanthracene and 2-methylnaphthalene.

The fluorescence maxima, lifetimes and quantum yields of the exciplex and the CT comples show continuous changes from room temperature to 77'K suggesting an identical fluorescent state of the exciplex and CT complex.

📜 SIMILAR VOLUMES

Magnetic modulation of fluorescence in a

Magnetic modulation of fluorescence in anthracene excited by high-energy photons: evidence for long-lived charge transfer states

✍ J. Klein; P. Martin; R. Voltz 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 343 KB

Kinetics and Mechanism of the Outer-Sphe

Kinetics and Mechanism of the Outer-Sphere Oxidation of Horse-Heart Cytochrome c by an Anionic Chromium(v) Complex – Kinetic Evidence for Precursor Formation and a Late Electron-Transfer Transition State

✍ Manuela Körner; Rudi van Eldik 📂 Article 📅 1999 🏛 John Wiley and Sons 🌐 English ⚖ 360 KB 👁 2 views

Keywords: Cytochrome c / Chromium(v) / Saturation kinetics / Separation of K and k ET / Volume profile / Kinetics The irreversible outer-sphere electron-transfer reaction High-pressure experiments were performed at two different pH values. The kinetic (stopped-flow) and thermodynamic between trans-