Fluorescence quenching method for measuring monomer consumption rates during free-radical crosslinking copolymerization

Determination of reaction activation ene

Determination of reaction activation energy during gelation in free radical crosslinking copolymerization using the steady-state fluorescence method

✍ Ö. Pekcan; Y. Yilmaz; O. Okay 📂 Article 📅 1996 🏛 John Wiley and Sons 🌐 English ⚖ 493 KB 👁 2 views

The steady-state fluorescence technique was used to study the sol-gel transition in free radical crosslinking copolymerization of methyl methacrylate and ethylene glycol dimethacrylate (EGDM). Pyrene methyl pivalate was used as a fluorescence probe for the in situ polymerization experiments. The tim