Excitation spectra have been taken near 191 nm of the intermixed C-X O-O and B-X 7-O transitions in NO. The relative positions of rotational lines of the two bands have been measured, and compared with tabulations in the literature. As a result, the absolute level positions can be specified with +\_
Fluorescence lifetimes of single rotational levels of no B2Π and C2Π
✍ Scribed by Koichi Tsukiyama; Toshiaki Munakata; Motowo Tsukakoshi; Takahiro Kasuya
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 347 KB
- Volume
- 137
- Category
- Article
- ISSN
- 0009-2614
No coin nor oath required. For personal study only.
✦ Synopsis
Fluorescence lifetimes of NO B 'lI I,z( v' = 7) and B zH,,2(v' =7)-C -?I (v' = 0) mixed states were measured in a free jet using pulsed tunable VUV laser light. The measured lifetimes ofthe B 'II I,z state were 389 and 423 ns for J' =OS and 1.5, respectively. It was found that lifetimes of the mixed states below the dissociation limit were substantially influenced by the mixing properties of the B and C states, whereas those above the dissociation limit are short because of predissociation.
📜 SIMILAR VOLUMES
The lifetime of NO C\*n(u' = 0) was measured by a single photon counting technique usïng a nanosecond light pulser. After deconvolution, the decay rate constant of the predissociating rotational levels, (0.7 + 0.1) X 10' s-l, and that of the non-predissociating rotational leveis. (7.2 + 2.0) X 10' s
The radiative lifetimes of the sijc lowest vibrational levels of Cz(d 3rIe) iere obtained from deuy time studies of the Cz(d 3n -a 3iI ) Swan band fluorescence excited by a pu!sed tunable dye laser. The lifetime was found to be 120 5 20 ns,%dep&udent of the vibrational level. From the experimental r
NO was irmdiated by a iow-pressure iodine discharge lamp which induced fluorescence from excited NO molecules. From analysis of fluorescence spectm it was found that the A %?(u = 5). C2H(u' = 1) and B 2H(u' = 8) states were excited by iodine atomic lines at 179.9,183.0 and 187.6 nm. respectively. By