Fluorescence of several tertiary aliphatm amines has been excited in the gas phase by absorption of 206.2 nm radiation, i.e. in the band corresponding to the x -x transition of N&J. No Quorescence Ives obtained from molecules having hydrogen or deuterium bonded directly to the nitrogen atom. The exp
โฆ LIBER โฆ
Fluorescence decay of tertiary aliphatic amines
โ Scribed by Clifford G. Cureton; Desmond V. O'Connor; David Phillips
- Publisher
- Elsevier Science
- Year
- 1980
- Tongue
- English
- Weight
- 275 KB
- Volume
- 73
- Category
- Article
- ISSN
- 0009-2614
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โฆ Synopsis
The fluorescence decay of the ternary ahphatic ammes trimethykmine (JMA). trietbylamine (TEA) and tri-n-pro@amine (ITPA) m the vapour phase excited between 260 and 215 nm has been shown to constst of a sir&e, wave!engthdepeudent, component when the first exctted state is uniquely excited, but two components when the fkst and second excited states are simultaneously exated. Thrs dual exponentiality persists at pressures as low as 10 mTorr, and it is argued that the two-component decay does not anse from coBisonal vibrational relaxation.
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