## Abstract Biliverdin dimethyl ester (**2**) in freshly prepared ethanolic solution showed fluorescence maxima at 710 and 770 nm which were shifted to 725 and 806 nm on monoprotonation. ฮฆ~F~ for **2** and 2 H ^+^ was similar at room temperature (1.1 ยท 10^โ4^ and 2.7 ยท 10^โ4^, respectively), and it
Fluorescence characteristics of phytochrome and biliverdins
โ Scribed by Song, Pill-Soon.; Chae, Quae.; Lightner, David A.; Briggs, Winslow R.; Hopkins, David.
- Book ID
- 120989801
- Publisher
- American Chemical Society
- Year
- 1973
- Tongue
- English
- Weight
- 366 KB
- Volume
- 95
- Category
- Article
- ISSN
- 0002-7863
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๐ SIMILAR VOLUMES
## Abstract Freshly prepared solutions of biliverdin dimethyl ester (**2**) in ethanol showed fluorescence maxima at 710 and 770 nm [ฮฆ~F~ = 1.1. 10^โ4^ (room temperature) and 5.0 10^โ4^ (77 K)]. The maxima of monoprotonated **2** at 77 K were shifted to 725 and 806 nm and the quantum yield was incr
## Abstract Biliverdin dimethyl ester (**1b;** IXฮฑ) and its XIIIฮฑ isomer **2b** have been isolated on a preparative scale after esterification of an isomeric mixture obtained by oxidation of bilirubin. Both isomers readily form solid solutions. The substitution patterns and the predominant helical