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Fluorescence and excitation spectra of the DO+, E1, and G1 states of the HgZn exciplex

โœ Scribed by J. Supronowicz; E. Hegazi; J.B. Atkinson; L. Krause

Publisher
Elsevier Science
Year
1994
Tongue
English
Weight
594 KB
Volume
222
Category
Article
ISSN
0009-2614

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โœฆ Synopsis

The high-lying DO+, El, and G 1 spin-orbit states of the HgZn exciplex were excited by pump and probe laser irradiation of a Hg-Zn vapor mixture in a quartz cell. The decays of these states gave rise to UV bound-free and visible bound-bound fluorescence spectra which were recorded with a monochromator, and scans of the probe dye laser produced excitation spectra in the region 4000-4600 A. Four new spectra were recorded and analyzed, yielding molecular constants for the various states. The new data also led to improved assignments of some previously reported HgZn spectra.

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