Conservation of angular momentum in RRKM
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A.S. Rodgers
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Article
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1994
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Elsevier Science
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English
β 498 KB
The "usual" implementation of the unimolecular rate constant in RRKM theory treats nonlinear molecules as pseudo-diatomits and thus does not conserve total angular momentum. A three-dimensional model for conservation of total angular momentum for vibrator transition states with the K rotational quan