Flow-through amperometric sensor for hydrogen peroxide monitoring in gaseous media
β Scribed by J. Kulys
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 471 KB
- Volume
- 9
- Category
- Article
- ISSN
- 0925-4005
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β¦ Synopsis
An amperometric flow-through sensor for the determination of hydrogen peroxide in gaseous media over the range 0.05-1.0 mg/m3 (0.03-0.66 ppmv) is described. The standard error of hydrogen peroxide determination is 3.5-Q?% at concentrations of 0.05-0.2 mg/m3 and 0.6-1.8% at higher hydrogen peroxide concentrations. The limit of hydrogen peroxide detection is 0.01 ppmv. The response time of the sensor at high concentrations of hydrogen peroxide is less than 1 mitt; the volume of gaseous media under investigation is l-l.5 1.
π SIMILAR VOLUMES
The hydrogen peroxide is oxidized at + 1.5 V vs. SCE at a glassy carbon electrode of the wall-jet type. The samples are diluted about 100 times in a dispersion coil before entering the amperometric detector. The calibration curve is linear from 10' to 1 M H&j,, when 5-rl samples are used. With 50-rl