Flow instability in capillary extrusion of plasticized poly(vinyl chloride)

✍ Scribed by Masayuki Yamaguchi

• Publisher: John Wiley and Sons
• Year: 2001
• Tongue: English
• Weight: 274 KB
• Volume: 82
• Category: Article
• ISSN: 0021-8995
• DOI: 10.1002/app.1961

✦ Synopsis

Abstract

Flow instability in a capillary extrusion is studied for a high molecular weight, plasticized poly(vinyl chloride) (PVC). The onset of melt fracture correlates with the long time relaxation ascribed to the generation and/or growth of PVC crystallites. An increase in the residence time in the cylinder leads to this long time relaxation and results in the melt fracture, although the apparent shear stress remains constant, irrespective of the residence time. The extrudate temperature and the species of the plasticizer also have a significant influence on the apparatus of the extruded products. © 2001 John Wiley & Sons, Inc. J Appl Polym Sci 82: 1277–1283, 2001