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Flourescence and decomposition of 1,4-Diazabicyclo [2.2.2] Octane in a glow discharge

✍ Scribed by Francoise Lahmani; R. Srinivasan

Publisher: Elsevier Science
Year: 1976
Tongue: English
Weight: 348 KB
Volume: 42
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(76)80563-5

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✦ Synopsis

Excitation of the title compound (DABCO) in a glow dlschargc gave at low voltage the fluorescence which has been assigned by others to an optically-forbrdden, low-lying, singlet state. with increasing voltage, the vrolet bands of the CN radical were also observed. Addition of He or AI strongly enhanced the intensity of the latter. It is believed that two excrtatron processes operate independently on the DABCO molecule to ,$ve the fluorescent state and a second state from which decomposition may lead to HCN as a major product.

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