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Flexible Synthetic Approach to a (S)-Norcamphor-Based Hydroperoxide: An Efficient Oxidant for Asymmetric Sulfoxidations.

✍ Scribed by Alessandra Lattanzi; Sandro Piccirillo; Arrigo Scettri


Publisher
John Wiley and Sons
Year
2006
Weight
21 KB
Volume
37
Category
Article
ISSN
0931-7597

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Flexible Synthetic Approach to a (S)-Nor
✍ Alessandra Lattanzi; Sandro Piccirillo; Arrigo Scettri 📂 Article 📅 2006 🏛 John Wiley and Sons 🌐 English ⚖ 132 KB

## Abstract The renewable tertiary (__S__)‐norcamphor‐based hydroperoxide **3** has been efficiently obtained by a simple 4‐step route. Remarkably, complete diastereocontrol was observed in the hydroperoxidation step. This oxidant, when used in the Ti‐catalyzed asymmetric sulfoxidation, showed to b