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Flexibility in the Self-Assembly of Silver Complexes: Coordination Polymers from Multi-Armed Pyridylmethyleneoxy Ligands

✍ Scribed by Steel, Peter J.; Fitchett, Christopher M.


Book ID
120179075
Publisher
Commonwealth Scientific and Industrial Research Organisation Publishing
Year
2013
Tongue
English
Weight
833 KB
Volume
66
Category
Article
ISSN
0004-9425

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## Abstract Two prototypical carbido anionic clusters, the prismatic [Rh~6~C(CO)~15~]^2–^ and the octahedral [Ru~6~C(CO)~16~]^2–^, can add two electrophilic Ag–NCMe^+^ fragments, which were exploited to condense the clusters with bifunctional heterocyclic ligands, such as pyrazine (pyz) or 4,4′‐bip