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Flavin-Catalyzed Oxidations of Sulfides and Amines with Molecular Oxygen.

✍ Scribed by Yasushi Imada; Hiroki Iida; Satoshi Ono; Shun-Ichi Murahashi

Publisher
John Wiley and Sons
Year
2003
Weight
147 KB
Volume
34
Category
Article
ISSN
0931-7597

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## Abstract For Abstract see ChemInform Abstract in Full Text.

Chloroperoxidase-catalyzed enantioselect
Chloroperoxidase-catalyzed enantioselective oxidation of methyl phenyl sulfide with dihydroxyfumaric acid/oxygen or ascorbic acid/oxygen as oxidants
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The chloroperoxidase catalyzed oxidation of methyl phenyl sulfide to (R)-methyl phenyl sulfoxide was investigated, both in batch and membrane reactors, using as oxidant H 2 O 2 , or O 2 in the presence of either dihydroxyfumaric acid or ascorbic acid. The effects of pH and nature and concentration o