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Flash Vacuum Thermolysis of N -(3- and 4-Pyridylmethylidene)- tert -butylamines: Mechanisms of Formation of Pyrrolopyridines and Naphthyridines

✍ Scribed by Justyna, Katarzyna; Leśniak, Stanisław; Nazarski, Ryszard B.; Rachwalski, Michał; Vu, Thien Y.; Huynh, Thi Kieu Xuan; Khayar, Saïd; Dargelos, Alain; Chrostowska, Anna; Wentrup, Curt

Book ID
121798755
Publisher
John Wiley and Sons
Year
2014
Tongue
English
Weight
818 KB
Volume
2014
Category
Article
ISSN
1434-193X

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Flash Vacuum Thermolysis of 4H-3,1-Benzoxathiin-4-thione: UV-Photoelectron Spectroscopy Characterization and Quantum Chemistry Studies
✍ Tomasz Drewnowski; Anna Chrostowska; Stanisław Leśniak; Alain Dargelos; Saïd Kha 📂 Article 📅 2008 🏛 John Wiley and Sons 🌐 German ⚖ 592 KB

## Abstract The mechanism of the reaction of 4__H__‐3,1‐benzoxathiin‐4‐thione (**3**) under flash vacuum thermolysis conditions has been studied by UV‐photoelectron spectra. It was shown that in the first step of the reaction at 400° **3** underwent the __Schönberg–Newman–Kwart__ rearrangement to g