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Flash Vacuum Thermolysis: First Gas-Phase Generation of Unhindered Silylidenephosphanes and Characterization by Photoelectron Spectroscopy

✍ Scribed by Lefèvre, V.; Ripoll, J. L.; Dat, Y.; Joantéguy, S.; Métail, V.; Chrostowska-Senio, A.; Pfister-Guillouzo, G.


Book ID
127127480
Publisher
American Chemical Society
Year
1997
Tongue
English
Weight
252 KB
Volume
16
Category
Article
ISSN
0276-7333

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✍ Kindermann, Markus Karl ;Kowski, Klaus ;Muchall, Heidi M. ;Rademacher, Paul 📂 Article 📅 1993 🏛 Wiley (John Wiley & Sons) 🌐 English ⚖ 613 KB

## Abstract The PE spectra of the 4,5‐dihydro‐3__H__‐pyrazoles 1, 2, of 2,5‐dihydro‐1,3,4‐oxadiazole 3, and 2,5‐dihydro‐1,3,4‐thiadiazole 4 have been recorded. Based on HAM/3, MNDO, AM1, and PM3 calculations, the ionization potentials have been assigned to molecular orbitals. The gas‐phase thermoly