lhe evaporation of a substrate through a hot tube at low pmssure (Flash Vacuum Thermolysis, FVTJ is a simple although effective technique for performing thermal chemistry.t In contrast to thermal reactions performed in the condensed phase, the high dilution of the gas phase suppresses unwanted side
Flash Thermolysis of Organic Compounds
✍ Scribed by Dr. Günther Seybold
- Book ID
- 102726053
- Publisher
- John Wiley and Sons
- Year
- 1977
- Tongue
- English
- Weight
- 758 KB
- Volume
- 16
- Category
- Article
- ISSN
- 0044-8249
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✦ Synopsis
Abstract
Flash thermolysis is a special form of gas‐phase thermolysis that is particularly suitable for the production and isolation of thermolabile reaction products. The theoretical basis and the instrumental requirements of the method are first given, and the preparative importance of flash thermolysis for the synthesis of thioketenes, allenes, arynes, highly strained ring systems, quinodimethanes, and other reactive compounds is then demonstrated with the aid of examples.
📜 SIMILAR VOLUMES
Cocaine is thermally labile and, in a series of remarkable thermal reactions, is cleanly partitioned among benzoic acid, N-methylpyrrole and methyl 3-butenoate. Unimolecular thermal behavior occupies a position of fundamental importance among those reactions that describe the chemistry of a molecul