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Flash photolysis studies of the reaction of NH2 radicals with NO

✍ Scribed by R. Lesclaux; Pham Van Khê; P. Dezauzier; J.C. Soulignac

Publisher
Elsevier Science
Year
1975
Tongue
English
Weight
443 KB
Volume
35
Category
Article
ISSN
0009-2614

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✦ Synopsis

The kinetics of the reaction NH2 + NO + N2 f Hz0 were studied, I;sins a conventional flash photolysis system. PI VdUC of k, = (1.1 s 0.2) x 10'0 E mole-' s-1 was obtained at room tempcralure and in the pressure ran_-2-700 ton in the presence of nitrogen. A slight negative tcmpcrature cocfiicient was obscrvcd between 300 and 500 K, equivalent to a ncgtive BCtivation cncrgy of 1.05 i 0.2 kcal mold' .

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